Synthesis and Characterization of Poly(styrene-co-acrylamide) Polymers Prior to Electrospinning

Oketola, Adebola A. and Torto, Nelson (2013) Synthesis and Characterization of Poly(styrene-co-acrylamide) Polymers Prior to Electrospinning. Advances in Nanoparticles, 02 (02). pp. 87-93. ISSN 2169-0510

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Abstract

Electrospun nanofibers present a new and rapidly growing research area due to their pronounced micro and nano characteristics associated with high surface area to volume ratio. Poly(styrene-co-acrylamide) and polystyrene polymers were synthesized by boiling temperature soap free emulsion polymerization in aqueous medium with potassium peroxosulphate as the initiator. The resulting polymers were dissolved in dimethylformamide and teterahydrofuran (DMF: THF) (4:1) to form polymer solutions that were electrospun into fiber mats with diameters ranging from 1.84 - 2.53 μm and 5.01 μm, respectively. The fibers were characterized by Fourier transform infrared spectroscopy (FTIR) equipped with universal ATR sampling accessory (4000 - 400 cm-1). The morphology and size were examined by a scanning electron miscroscope (SEM) and the thermal properties by thermogravimetric analysis (TGA). The FTIR spectra of the poly(styrene-co-acrylamide) revealed the presence of acrylamide on the polystyrene chain. Thus, surface modification of polystyrene with acrylamide is possible in a single step polymerization reaction prior to electrospinning.

Item Type: Article
Subjects: STM Digital Press > Medical Science
Depositing User: Unnamed user with email support@stmdigipress.com
Date Deposited: 31 May 2023 06:29
Last Modified: 06 Sep 2024 08:29
URI: http://publications.articalerewriter.com/id/eprint/977

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